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Journal article

Electrophilic amination of 2-azadienes

Abstract:

2-Azadienes 1 bearing a trialkylsilyloxy group on position 3 can be regarded as carboxylic acid synthons. Their cycloadditions with several classes of nitroso compounds have been studied in detail as well as the transformation of the adducts into α-amino acids. The study showed that arylnitroso compounds such as nitrosobenzene reacted with 2-azadienes to give adducts that are potential precursors of α-N-arylamino acids. We have outlined an important limitation to the use of α-chloronitroso co...

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Publication status:
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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
TETRAHEDRON
Volume:
52
Issue:
21
Pages:
7585-7598
Publication date:
1996-05-20
DOI:
ISSN:
0040-4020
Keywords:
Pubs id:
pubs:45142
UUID:
uuid:ce102a13-339f-4c7a-89a2-6e52af6fca1e
Local pid:
pubs:45142
Source identifiers:
45142
Deposit date:
2012-12-19

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