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Nanoparticle-Impact Experiments are Highly Sensitive to the Presence of Adsorbed Species on Electrode Surfaces

Abstract:

We theoretically and experimentally investigate the influence of partial surface blocking on the electrochemistry of nanoparticles impacting at an electrode. To this end, we introduce an analytical model for the adsorption of single blocking molecules on the electrode and calculate the resulting fractional electrode coverage. We find that even small amounts of adsorbed molecules can fully suppress detection of impacts of nanoparticles while the electrode characteristics in the detection of el...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/celc.201402014

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More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Chemelectrochem
Volume:
1
Issue:
6
Pages:
1057-1062
Publication date:
2014-06-11
DOI:
ISSN:
2196-0216
Keywords:
Pubs id:
pubs:477845
UUID:
uuid:cd3f4f36-b654-4809-9029-9c13f4205c02
Local pid:
pubs:477845
Source identifiers:
477845
Deposit date:
2014-08-12

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