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The synthesis of (+/-)-heliotridane and (6S,7S)-dihydroxyheliotridane via sequential hydrogen atom abstraction and cyclisation

Abstract:
Treatment of N-(3-bromo-3-butenyl)pyrrolidine derivatives with tributyltin hydride and AIBN leads to hydrogen atom transfer of the intermediate vinyl radicals to give α-amino radicals which then cyclise stereoselectively yielding pyrrolizidines 1 and 13.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
TETRAHEDRON LETTERS More from this journal
Volume:
37
Issue:
32
Pages:
5825-5828
Publication date:
1996-08-05
DOI:
ISSN:
0040-4039
Language:
English
Pubs id:
pubs:55248
UUID:
uuid:cd2a4738-2d6e-4abb-aed7-794b1a61a8f0
Local pid:
pubs:55248
Source identifiers:
55248
Deposit date:
2012-12-19

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