Journal article
Resolving a discrepancy in diffusion potentials, with a case study for Li-Ion batteries
- Abstract:
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Overpotentials induced by liquid-phase composition variation can be important when electrochemical devices are operated at high current. The dominant models that describe such ‘diffusion potentials’ are Nernst–Planck (dilute-solution) theory and Onsager–Stefan–Maxwell (concentrated-solution) theory. Nernst–Planck flux laws emerge from Onsager–Stefan–Maxwell laws in the limit of high electrolyte dilution, and the material properties involved come into agreement. The two models yield different ...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's Version
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(pdf, 360.8KB)
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- Publisher copy:
- 10.1149/2.0451608jes
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Authors
Funding
Bibliographic Details
- Publisher:
- Electrochemical Society Publisher's website
- Journal:
- Journal of the Electrochemical Society Journal website
- Publication date:
- 2016-05-05
- DOI:
- URN:
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uuid:cd2354c9-854a-4400-b006-f26f499470b4
- Source identifiers:
-
623923
- Local pid:
- pubs:623923
Terms of use
- Copyright holder:
- Monroe et al
- Copyright date:
- 2016
- Notes:
- © The Author(s) 2016. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY,http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. [DOI:10.1149/2.0451608jes] All rights reserved.
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