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An R(1ρ) expression for a spin in chemical exchange between two sites with unequal transverse relaxation rates.

Abstract:

An analytical expression is derived for the rotating frame relaxation rate, R(1ρ), of a spin exchanging between two sites with different transverse relaxation times. A number of limiting cases are examined, with the equation reducing to formulae derived previously under the assumption of equivalent relaxation rates at each site. The measurement of a pair off-resonance R(1ρ) values, with the carrier displaced equally on either side of the observed correlation, forms the basis of one of the app...

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Publication status:
Published

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Publisher copy:
10.1007/s10858-012-9694-6

Authors


Baldwin, AJ More by this author
Journal:
Journal of biomolecular NMR
Volume:
55
Issue:
2
Pages:
211-218
Publication date:
2013-02-05
DOI:
EISSN:
1573-5001
ISSN:
0925-2738
URN:
uuid:cd191511-55d2-4519-afd2-4c99397a9bf0
Source identifiers:
386640
Local pid:
pubs:386640

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