- Abstract:
-
An analytical expression is derived for the rotating frame relaxation rate, R(1ρ), of a spin exchanging between two sites with different transverse relaxation times. A number of limiting cases are examined, with the equation reducing to formulae derived previously under the assumption of equivalent relaxation rates at each site. The measurement of a pair off-resonance R(1ρ) values, with the carrier displaced equally on either side of the observed correlation, forms the basis of one of the app...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1007/s10858-012-9694-6
-
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- Journal:
- Journal of biomolecular NMR
- Volume:
- 55
- Issue:
- 2
- Pages:
- 211-218
- Publication date:
- 2013-02-05
- DOI:
- EISSN:
-
1573-5001
- ISSN:
-
0925-2738
- URN:
-
uuid:cd191511-55d2-4519-afd2-4c99397a9bf0
- Source identifiers:
-
386640
- Local pid:
- pubs:386640
- Language:
- English
- Keywords:
- Copyright date:
- 2013
Journal article
An R(1ρ) expression for a spin in chemical exchange between two sites with unequal transverse relaxation rates.
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