- Abstract:
-
The large-scale synthesis of two highly methylated fluorene ligands is reported, and the synthesis and characterization of three organometallic derivatives are reported. Starting with 1,2,3,4-tetramethylbenzene, 1,2,3,4,5,6,7,8-octa- and 1,2,3,4,5,6,7,8,9-nonamethylfluorene (Flu"H and Flu*H) have been synthesized in overall yields of above 50%. Both fluorenes may be deprotonated at the 9 position to yield useful organometallic synthons; the Sn derivative, Flu*SnMe3, is synthesized using this ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/om0603666
-
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- Journal:
- ORGANOMETALLICS
- Volume:
- 25
- Issue:
- 18
- Pages:
- 4279-4285
- Publication date:
- 2006-08-28
- DOI:
- EISSN:
-
1520-6041
- ISSN:
-
0276-7333
- URN:
-
uuid:ccfcec92-f271-4bb8-a114-c6db12e22f57
- Source identifiers:
-
51289
- Local pid:
- pubs:51289
- Language:
- English
- Copyright date:
- 2006
Journal article
Bulk synthesis of octa- and nonamethylfluorene (Flu '' H and Flu*H) and the characterization of the organometallic derivatives Flu*SnMe3, [(FeCp)(2)Flu*H][PF6](2), and [(FeCp)(2)Flu '' H][PF6](2)
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