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Multimetallic Arrays: Symmetrical and Unsymmetrical Bi-, Tri-, and Tetrametallic Organometallic Complexes of Ruthenium(II) and Osmium(II)

Abstract:: The cationic complex [Ru(C(C=CPh)=CHPhXS2CNC4H 8NH2)(CO)(PPh3)2]+ was prepared from the reaction of [Ru(C(C=CPh)=CHPh)Cl(CO)(BTD)(PPh 3)2] (BID = 2,1,3-benzothiadiazole) with the zwitterionic dithiocarbamate H2NC4H8NCS2 and characterized structurally. In situ generation of the metalladithiocarbamate [Ru(C(C=Ph)=CHPh)(S2CNC4H8NCS2XCO)(PPh 3)2] followed by treatment with [Ru(C(C=CPh)=CHPh)Cl(CO) (BTD)(PPh3)2] yielded the symmetrical bimetallic complex [{Ru(C(C=Ph)=CHPh)(CO)(PPh3)2}2(S 2CNC4H8NC...
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Publication status:: Published

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APA Style

Macgregor, M., Hogarth, G., Thompson, A., & Wilton-Ely, J. (2009). Multimetallic Arrays: Symmetrical and Unsymmetrical Bi-, Tri-, and Tetrametallic Organometallic Complexes of Ruthenium(II) and Osmium(II). ORGANOMETALLICS, 28(1), 197–208.

MLA Style

Macgregor, M., et al. “Multimetallic Arrays: Symmetrical and Unsymmetrical Bi-, Tri-, and Tetrametallic Organometallic Complexes of Ruthenium(II) and Osmium(II).” ORGANOMETALLICS, vol. 28, no. 1, 2009, pp. 197–208.

Chicago Style

Macgregor, M, G Hogarth, A Thompson, and J Wilton-Ely. 2009. “Multimetallic Arrays: Symmetrical and Unsymmetrical Bi-, Tri-, and Tetrametallic Organometallic Complexes of Ruthenium(II) and Osmium(II).” ORGANOMETALLICS 28 (1): 197–208.
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Publisher copy:: 10.1021/om800686f

Authors

+ Macgregor, M More by this author

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Author

+ Hogarth, G More by this author

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Author

+ Thompson, A More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Inorganic Chemistry

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Author

+ Wilton-Ely, J More by this author

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Author

Bibliographic Details

Journal:: ORGANOMETALLICS
Volume:: 28
Issue:: 1
Pages:: 197-208
Publication date:: 2009-01-12
DOI:: 10.1021/om800686f
EISSN:: 1520-6041
ISSN:: 0276-7333

Item Description

Language:: English
Pubs id:: pubs:117181
UUID:: uuid:ccfa0a39-b6f7-4841-8281-552cc052cb05
Local pid:: pubs:117181
Source identifiers:: 117181
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2009

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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