Journal article icon

Journal article

The mechanism of hydrazine electro-oxidation revealed by platinum microelectrodes: role of residual oxides.

Abstract:

The electrochemistry of hydrazine at platinum has been re-evaluated by an investigation using microelectrodes. Platinum oxides remaining from preceding oxidative scans results in hydrazine oxidation occurring up to ca. 400 mV more cathodic than at an oxide-free Pt electrode. The observed voltammetry at oxidised or 'activated' platinum electrodes was found to be a function of the immersion time (time since 'activation') and pH. Differences between phosphate, sulphate and acetate-based electrol...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1039/c0cp02261f

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP More from this journal
Volume:
13
Issue:
12
Pages:
5279-5287
Publication date:
2011-03-01
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Language:
English
Pubs id:
pubs:120154
UUID:
uuid:ccdc5a8f-987c-45e6-924e-cd6beac92c74
Local pid:
pubs:120154
Source identifiers:
120154
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP