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Asymmetric fluorocyclizations of alkenes.

Abstract:

Conspectus The vicinal fluorofunctionalization of alkenes is an attractive transformation that converts feedstock olefins into valuable cyclic fluorinated molecules for application in the pharmaceutical, agrochemical, medical, and material sectors. The challenges associated with asymmetric fluorocyclizations induced by F(+) reagents are distinct from other types of halocyclizations. Processes initiated by the addition of an F(+) reagent onto an alkene do not involve the reversible formation o...

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Publisher copy:
10.1021/ar500282z

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Publisher:
American Chemical Society
Journal:
Accounts of chemical research
Volume:
47
Issue:
12
Pages:
3560-3570
Publication date:
2014-12-05
DOI:
EISSN:
1520-4898
ISSN:
0001-4842
URN:
uuid:cc42a62d-f06c-4c41-ae8f-2670f65738af
Source identifiers:
490889
Local pid:
pubs:490889
Language:
English

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