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Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate

Abstract:
Propylene carbonate is an excellent solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions, allowing a variety of β-S-aldehydes and alkynes to be combined in high yields, to deliver enone products. The effective use of propylene carbonate removes the need to employ dichloroethane as solvent. © 2011 The Royal Society of Chemistry.
Publication status:
Published

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Publisher copy:
10.1039/c1gc15293a
Journal:
GREEN CHEMISTRY
Volume:
13
Issue:
8
Pages:
1980-1982
Publication date:
2011-01-01
DOI:
EISSN:
1463-9270
ISSN:
1463-9262
Language:
English
Pubs id:
pubs:170282
UUID:
uuid:cbff132d-81e4-408f-ab6f-0e60233f2ac5
Local pid:
pubs:170282
Source identifiers:
170282
Deposit date:
2012-12-19

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