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Manganese(III)-mediated radical cyclisations for the (Z)-selective synthesis of exo-alkylidene pyrrolidinones and pyrrolidines.

Abstract:
The cyclisation of alkynyl amido- and amino-malonates in the presence of manganese(III) acetate gives exo-alkylidene pyrrolidinones and pyrrolidines with a preference for the (Z)-alkene product isomer.
Publication status:
Published

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Publisher copy:
10.1039/c2cc32382f

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Chemical Communications
Volume:
48
Issue:
52
Pages:
6496-6498
Publication date:
2012-07-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
332758
Language:
English
Keywords:
Pubs id:
pubs:332758
UUID:
uuid:cb8ac399-3b53-4504-aaa2-0da2fadf3222
Local pid:
pubs:332758
Deposit date:
2012-12-19

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