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Luminescent Pt(II)(bipyridyl)(diacetylide) chromophores with pendant binding sites as energy donors for sensitised near-infrared emission from lanthanides: structures and photophysics of Pt(II)/Ln(III) assemblies.

Abstract:

The complexes [Pt(bipy){CC-(4-pyridyl)}(2)] (1) and [Pt(tBu(2)bipy){CC-(4-pyridyl)}(2)] (2) and [Pt(tBu(2)-bipy)(CC-phen)(2)] (3) all contain a Pt(bipy)(diacetylide) core with pendant 4-pyridyl (1 and 2) or phenanthroline (3) units which can be coordinated to {Ln(diketonate)(3)} fragments (Ln = a lanthanide) to make covalently-linked Pt(II)/Ln(III) polynuclear assemblies in which the Pt(II) chromophore, absorbing in the visible region, can be used to sensitise near-infrared luminescence from ...

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Publication status:
Published

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Publisher copy:
10.1002/chem.200600698

Authors


Ronson, TK More by this author
Lazarides, T More by this author
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Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Volume:
12
Issue:
36
Pages:
9299-9313
Publication date:
2006-12-05
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
URN:
uuid:cb662fd0-4d7b-4780-adab-10d9801b057f
Source identifiers:
46790
Local pid:
pubs:46790

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