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Synthesis and characterization of a bimetallic boratabenzene cobalt complex

Abstract:

Reaction of 1,4-(BBr 2) 2C 6H 4 with cobaltocene gives a bimetallic cobalt complex with cyclopentadienyl and boratabenzene ligands. Oxidation allows the dicationic dicobalt(III) complex to be isolated; the bis(hexafluorophosphate) salt has been structurally characterized. Variable-temperature magnetic susceptibility measurements on the neutral dicobalt(II) complex showed substantial deviation from the Curie -Weiss law; a fit to the Bleaney-Bowers equation for a singlet ground state and a trip...

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Publication status:
Published

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Publisher copy:
10.1021/om049750y

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS More from this journal
Volume:
23
Issue:
16
Pages:
3808-3813
Publication date:
2004-08-02
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Language:
English
Pubs id:
pubs:51178
UUID:
uuid:cb3069a8-bcf1-469c-921c-6d1c37db87b1
Local pid:
pubs:51178
Source identifiers:
51178
Deposit date:
2012-12-19

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