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Synthesis and characterization of a bimetallic boratabenzene cobalt complex

Abstract:: Reaction of 1,4-(BBr 2) 2C 6H 4 with cobaltocene gives a bimetallic cobalt complex with cyclopentadienyl and boratabenzene ligands. Oxidation allows the dicationic dicobalt(III) complex to be isolated; the bis(hexafluorophosphate) salt has been structurally characterized. Variable-temperature magnetic susceptibility measurements on the neutral dicobalt(II) complex showed substantial deviation from the Curie -Weiss law; a fit to the Bleaney-Bowers equation for a singlet ground state and a trip...
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APA Style

Hascall, T., Beck, V., Barlow, S., Cowley, A., & O'Hare, D. (2004). Synthesis and characterization of a bimetallic boratabenzene cobalt complex. ORGANOMETALLICS, 23(16), 3808–3813.

MLA Style

Hascall, T., et al. “Synthesis and Characterization of a Bimetallic Boratabenzene Cobalt Complex.” ORGANOMETALLICS, vol. 23, no. 16, 2004, pp. 3808–13.

Chicago Style

Hascall, T, V Beck, S Barlow, A Cowley, and D O'Hare. 2004. “Synthesis and Characterization of a Bimetallic Boratabenzene Cobalt Complex.” ORGANOMETALLICS 23 (16): 3808–13.
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Publisher copy:: 10.1021/om049750y

Authors

+ Hascall, T More by this author

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Author

+ Beck, V More by this author

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Author

+ Barlow, S More by this author

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+ Cowley, A More by this author

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+ O'Hare, D More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Inorganic Chemistry

Role:

Author

Bibliographic Details

Journal:: ORGANOMETALLICS
Volume:: 23
Issue:: 16
Pages:: 3808-3813
Publication date:: 2004-08-02
DOI:: 10.1021/om049750y
EISSN:: 1520-6041
ISSN:: 0276-7333

Item Description

Language:: English
Pubs id:: pubs:51178
UUID:: uuid:cb3069a8-bcf1-469c-921c-6d1c37db87b1
Local pid:: pubs:51178
Source identifiers:: 51178
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2004

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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