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Desolvation of a novel microporous hydrogen-bonded framework: Characterization by in situ single-crystal and powder X-ray diffraction

Abstract:
Despite significant structural rearrangement upon desolvation of a three-dimensional molecular framework of hexaaquacobalt cations and redox- active functionalized tetrathiafulvalene anions (see the picture; the area filled with water molecules is shown in gray), monocrystallinity and microporosity are retained. X-ray analyses show that a unique combination of hydrogen bonds and π ·· π interactions within the framework gives this material a structural flexibility not seen in zeolites or their analogues.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION More from this journal
Volume:
37
Issue:
22
Pages:
3158-3160
Publication date:
1998-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Language:
English
Keywords:
Pubs id:
pubs:36779
UUID:
uuid:cb165068-cfe4-46b3-b144-2cb11c4e9daa
Local pid:
pubs:36779
Source identifiers:
36779
Deposit date:
2012-12-19

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