Journal article
Neutral redox-active hydrogen- and halogen-bonding [2]rotaxanes for the electrochemical sensing of chloride.
- Abstract:
-
The first examples of redox-active ferrocene-functionalised neutral [2]rotaxanes have been synthesised via chloride anion templation. (1)H NMR spectroscopic titrations reveal that these [2]rotaxane host systems recognize chloride selectively over other halides and oxoanions in highly-competitive aqueous media. By replacing the hydrogen bonding prototriazole units of the rotaxane axle component with iodotriazole halogen bond-donor groups, the degree of chloride selectivity of the [2]rotaxanes ...
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- Publication status:
- Published
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Bibliographic Details
- Publisher:
- Royal Society of Chemistry
- Journal:
- Dalton transactions (Cambridge, England : 2003)
- Volume:
- 43
- Issue:
- 46
- Pages:
- 17274-17282
- Publication date:
- 2014-12-01
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
Item Description
- Language:
- English
- Pubs id:
-
pubs:486593
- UUID:
-
uuid:cb14774a-4e51-4b23-80b3-307686a49633
- Local pid:
- pubs:486593
- Source identifiers:
-
486593
- Deposit date:
- 2014-10-16
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- Copyright date:
- 2014
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