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A theoretical and experimental approach to the adiabaticity of diffusional electron transfer processes. Electroreduction of 2-nitropropane on mercury microelectroelectrodes

Abstract:

A theoretical and experimental approach to the degree of adiabaticity of electrode processes is considered for the case where the electroactive species of the redox couple move freely in solution. Within a transition state-like framework, the adiabatic effect on the activation energy of electron transfer is included through the theory developed by Schmickler (W. Schmickler, J. Electroanal. Chem. 204 (1986) 31). The effect on the probability of electron tunnelling is also incorporated accordin...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
704
Pages:
102-110
Publication date:
2013-09-01
DOI:
ISSN:
1572-6657
Source identifiers:
417276
Language:
English
Keywords:
Pubs id:
pubs:417276
UUID:
uuid:caf00c9d-e9a7-4cc3-ad59-b651b02cf325
Local pid:
pubs:417276
Deposit date:
2013-11-16

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