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A theoretical and experimental approach to the adiabaticity of diffusional electron transfer processes. Electroreduction of 2-nitropropane on mercury microelectroelectrodes

Abstract:

A theoretical and experimental approach to the degree of adiabaticity of electrode processes is considered for the case where the electroactive species of the redox couple move freely in solution. Within a transition state-like framework, the adiabatic effect on the activation energy of electron transfer is included through the theory developed by Schmickler (W. Schmickler, J. Electroanal. Chem. 204 (1986) 31). The effect on the probability of electron tunnelling is also incorporated accordin...

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Publication status:
Published

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Authors


Laborda, E More by this author
Suwatchara, D More by this author
Batchelor-McAuley, C More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
704
Pages:
102-110
Publication date:
2013-09-01
DOI:
ISSN:
1572-6657
URN:
uuid:caf00c9d-e9a7-4cc3-ad59-b651b02cf325
Source identifiers:
417276
Local pid:
pubs:417276

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