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Synthesis and structure of alkaline earth silicon nitrides: BaSiN(2), SrSiN(2), and CaSiN(2).

Abstract:

The alkaline earth silicon nitrides AESiN(2) (AE = Ca, Sr, Ba) are reported, synthesized as clear, colorless, single crystals from molten sodium at 900-1100 degrees C or, in the cases of BaSiN(2) and SrSiN(2), as white powders by reacting powdered intermetallics AESi with flowing anhydrous ammonia at 550-1000 degrees C. Structures were determined from single-crystal X-ray diffraction measurements at 150 K: BaSiN(2) crystallizes in space group Cmca (No. 64) with a = 5.6046(1) A, b = 11.3605(3)...

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Publication status:
Published

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Publisher copy:
10.1021/ic049901p

Authors


Mallinson, PM More by this author
Orchard, HJ More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Inorganic chemistry
Volume:
43
Issue:
13
Pages:
3998-4006
Publication date:
2004-06-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:caac495f-3be0-417f-ae7a-0d73c54c99db
Source identifiers:
32749
Local pid:
pubs:32749
Language:
English

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