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Communication: Gas-phase structural isomer identification by Coulomb explosion of aligned molecules

Abstract:

The gas-phase structures of four difluoroiodobenzene and two dihydroxybromobenzene isomers were identified by correlating the emission angles of atomic fragment ions created, following femtosecond laser-induced Coulomb explosion. The structural determinations were facilitated by confining the most polarizable axis of each molecule to the detection plane prior to the Coulomb explosion event using one-dimensional laser-induced adiabatic alignment. For a molecular target consisting of two difluo...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1063/1.5023441

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Christiansen, L More by this author
Johansen, RR More by this author
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Grant:
FP7 ITN ’ICONIC’, Project No. 238671; Project No. 320459, DropletControl; H2020 MEDEA; Marie Skodowska-Curie Grant Agreement No. 641789
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Grant:
PNPAS award and miniIPS Grant No. ST/J002895/1
Publisher:
AIP Publishing Publisher's website
Journal:
Journal of Chemical Physics Journal website
Volume:
148
Issue:
9
Pages:
Article: 091102
Publication date:
2018-03-01
Acceptance date:
2018-02-13
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
Pubs id:
pubs:829608
URN:
uri:ca8539e3-4420-4487-aa58-fc8432bf2fc9
UUID:
uuid:ca8539e3-4420-4487-aa58-fc8432bf2fc9
Local pid:
pubs:829608

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