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Spectroscopy and dynamics of rare gas-spherical top complexes .3. The infrared spectrum of the nu(3) band of Ne-SiH4 (j=1<-1 and j=2<-1 transitions)

Abstract:

The infrared spectrum of the rare gas-spherical top complex Ne-SiH4 has been recorded in a supersonic jet in the region of the SiH4 ν3, triply degenerate stretching vibration at ∼2189 cm-1. The Ne-SiH4 spectrum is complex with no obvious regular band structure; a previous paper has reported the assignment and analysis of bands correlating with the SiH4 R(0) (K=0←0, K =1←0) and P(1) (K=0←0, K=0←1) transitions. This paper concludes the study of Ne-SiH4, with the assignment and analysis of bands...

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Publication status:
Published

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Publisher copy:
10.1063/1.474700

Authors


Brookes, MD More by this author
Hughes, DJ More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
107
Issue:
8
Pages:
2738-2751
Publication date:
1997-08-22
DOI:
ISSN:
0021-9606
URN:
uuid:ca705ccb-6fba-48dc-8796-ceb31a3a350d
Source identifiers:
45689
Local pid:
pubs:45689
Language:
English

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