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Cationic terminal borylenes by halide abstraction: synthesis and spectroscopic and structural characterization of an Fe=B double bond.

Abstract:
The synthesis and the spectroscopic and structural characterization of the cationic terminal borylene complex [Cp*Fe(CO)2(BMes)]+ are reported. Halide abstraction from the corresponding bromoboryl species using Na[BAr f4] generates the borylene as the [BAr f4]- salt in ca. 50% yield. Analyses of IR, NMR, crystallographic, and DFT data are consistent with the presence of an Fe=B double bond.
Publication status:
Published

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Publisher copy:
10.1021/ja0346936

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Journal of the American Chemical Society More from this journal
Volume:
125
Issue:
21
Pages:
6356-6357
Publication date:
2003-05-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:46034
UUID:
uuid:ca6c9e29-d285-4f10-8fa3-01c171554896
Local pid:
pubs:46034
Source identifiers:
46034
Deposit date:
2012-12-19

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