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Tetrameric iridium hydride-rich clusters formed under hydrogenation conditions.

Abstract:
(Chemical Equation Presented) Butterfly clusters: Hydrogenation of a cationic iridium complex with the sterically bulky N-ligand tetrahydroquinoline (thq) leads to the formation of two distinct tetrameric polyhydrides (see scheme; Ir green, N blue, P purple), which differ by exchanging one thq ligand for hydride. Both complexes have butterfly structures, with similar core geometries, but markedly different hinge angles (40.8° for 1 and 9.1° for 2). © 2009 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200804484

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Yurtsever, M More by this author
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Journal:
Angewandte Chemie (International ed. in English)
Volume:
48
Issue:
3
Pages:
582-585
Publication date:
2009
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:ca56f518-a8fe-421f-b024-9624ba325fea
Source identifiers:
34515
Local pid:
pubs:34515

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