Thesis
Synthetic and mechanistic studies of arylsilane oxidation
- Abstract:
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In this thesis, we study arylsilane oxidation from both a synthetic and a mechanistic perspective. Building upon previous work within our group, we demonstrate in an early chapter that arylhydrosilanes are surprisingly reactive to oxidation. This disproves the previous assumptions of the Tamao oxidation and provides new insights into the mechanism of the reaction. Furthermore, we find that the best substrates for oxidation are arylmethoxysilanes, and we describe rapid and efficient synt...
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Bibliographic Details
- Publication date:
- 2013
- Type of award:
- DPhil
- Level of award:
- Doctoral
- Awarding institution:
- University of Oxford
Item Description
- Language:
- English
- Keywords:
- Subjects:
- UUID:
-
uuid:ca3cfee8-305d-402a-bf6d-6417f7790289
- Local pid:
- ora:12541
- Deposit date:
- 2016-07-14
Terms of use
- Copyright holder:
- Rayment, E
- Copyright date:
- 2013
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