- Abstract:
-
The alternating copolymerization of CO2/epoxides is a useful means to incorporate high levels of carbon dioxide into polymers. The reaction is generally proposed to occur by bimetallic or bicomponent pathways. Here, the first indium catalysts are presented, which are proposed to operate by a distinct mononuclear pathway. The most active and selective catalysts are phosphasalen complexes, which feature ligands comprising two iminophosphoranes linked to sterically hindered ortho-phenolates. The...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's Version
- Files:
-
-
(pdf, 2.2mb)
-
(pdf, 5.9mb)
-
- Publisher copy:
- 10.1021/jacs.8b01920
-
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- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 140
- Issue:
- 22
- Pages:
- 6893–6903
- Publication date:
- 2018-05-21
- DOI:
- EISSN:
-
1520-5126
- ISSN:
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0002-7863
- Pubs id:
-
pubs:854042
- URN:
-
uri:ca108452-330a-4090-83ec-7ddad047492e
- UUID:
-
uuid:ca108452-330a-4090-83ec-7ddad047492e
- Local pid:
- pubs:854042
- Language:
- English
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2018
- Notes:
- © 2018 American Chemical Society. This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited. Supporting information for this article is available from ACS Publications at: https://pubs.acs.org/doi/suppl/10.1021/jacs.8b01920
Journal article
Indium catalysts for low-pressure CO2/epoxide ring-opening copolymerization: Evidence for a mononuclear mechanism?
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