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Indium catalysts for low-pressure CO2/epoxide ring-opening copolymerization: Evidence for a mononuclear mechanism?

Abstract:

The alternating copolymerization of CO2/epoxides is a useful means to incorporate high levels of carbon dioxide into polymers. The reaction is generally proposed to occur by bimetallic or bicomponent pathways. Here, the first indium catalysts are presented, which are proposed to operate by a distinct mononuclear pathway. The most active and selective catalysts are phosphasalen complexes, which feature ligands comprising two iminophosphoranes linked to sterically hindered ortho-phenolates. The...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's Version

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Publisher copy:
10.1021/jacs.8b01920

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
ORCID:
0000-0002-5543-6595
White, AJP More by this author
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
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Funding agency for:
Thevenon, A
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Funding agency for:
Thevenon, A
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Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
140
Issue:
22
Pages:
6893–6903
Publication date:
2018-05-21
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Pubs id:
pubs:854042
URN:
uri:ca108452-330a-4090-83ec-7ddad047492e
UUID:
uuid:ca108452-330a-4090-83ec-7ddad047492e
Local pid:
pubs:854042
Language:
English

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