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Relating mechanical properties and chemical bonding in an inorganic-organic framework material: a single-crystal nanoindentation study.

Abstract:

We report the application of nanoindentation and atomic force microscopy to establish the fundamental relationships between mechanical properties and chemical bonding in a dense inorganic-organic framework material: Ce(C(2)O(4))(HCO(2)), 1. Compound 1 is a mixed-ligand 3-D hybrid which crystallizes in an orthorhombic space group, in which its three basic building blocks, i.e. the inorganic metal-oxygen-metal (M-O-M) chains and the two organic bridging ligands, (oxalate and formate) are all or...

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Publication status:
Published

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Publisher copy:
10.1021/ja9060307

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Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Role:
Author
Journal:
Journal of the American Chemical Society More from this journal
Volume:
131
Issue:
40
Pages:
14252-14254
Publication date:
2009-10-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:369797
UUID:
uuid:c9e2429e-b0b1-4371-a5e7-da6cc30d39a6
Local pid:
pubs:369797
Source identifiers:
369797
Deposit date:
2013-11-16

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