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Journal article

Dynamic theory of liquid junction potentials.

Abstract:

A Nernst-Planck-Poisson finite difference simulation system is used to model the dynamic evolution of a liquid junction from a nonequilibrium initial condition to a condition of steady potential difference, in a linear semi-infinite space. Liquid junctions of Lingane's type 1 (monophasic, unequal concentration) and type 2 (bi-ionic potential; biphasic, equal concentration) are considered, for the sake of simplicity. Analysis of the results shows consistency with known and novel asymptotic sol...

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Publication status:
Published

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Publisher copy:
10.1021/jp908024s

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
journal of physical chemistry. B More from this journal
Volume:
114
Issue:
1
Pages:
187-197
Publication date:
2010-01-01
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Language:
English
Pubs id:
pubs:35009
UUID:
uuid:c9d9dce3-f408-411c-89b5-f9440e232072
Local pid:
pubs:35009
Source identifiers:
35009
Deposit date:
2012-12-19

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