Journal article
Dynamic theory of liquid junction potentials.
- Abstract:
-
A Nernst-Planck-Poisson finite difference simulation system is used to model the dynamic evolution of a liquid junction from a nonequilibrium initial condition to a condition of steady potential difference, in a linear semi-infinite space. Liquid junctions of Lingane's type 1 (monophasic, unequal concentration) and type 2 (bi-ionic potential; biphasic, equal concentration) are considered, for the sake of simplicity. Analysis of the results shows consistency with known and novel asymptotic sol...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- journal of physical chemistry. B
- Volume:
- 114
- Issue:
- 1
- Pages:
- 187-197
- Publication date:
- 2010-01-01
- DOI:
- EISSN:
-
1520-5207
- ISSN:
-
1520-6106
Item Description
- Language:
- English
- Pubs id:
-
pubs:35009
- UUID:
-
uuid:c9d9dce3-f408-411c-89b5-f9440e232072
- Local pid:
- pubs:35009
- Source identifiers:
-
35009
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2010
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