Journal article
Dual doping effects (site blockage and electronic promotion) imposed by adatoms on Pd nanocrystals for catalytic hydrogen production.
- Abstract:
- Three distinctive doping effects to modify the electronic and geometric properties of Pd nanocrystals for HCOOH decomposition to H2/CO2 are presented: Bi atoms take preferable residence on higher index sites, which leads to a reduction in HCOOH dehydration; Te atoms dwell favourably on terrace sites, which reduces the rate of dehydrogenation; Ag atoms, without site specificity, induce strong electronic effects to promote the activity on the dwindling number of surface Pd sites at high coverage.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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Authors
Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Chemical Communications Journal website
- Volume:
- 51
- Issue:
- 1
- Pages:
- 46-49
- Publication date:
- 2015-01-01
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
Item Description
- Language:
- English
- Pubs id:
-
pubs:485489
- UUID:
-
uuid:c996446c-7f7a-4f98-8020-902138fe7870
- Local pid:
- pubs:485489
- Source identifiers:
-
485489
- Deposit date:
- 2014-10-04
Terms of use
- Copyright holder:
- Jones et al
- Copyright date:
- 2015
- Notes:
- The full text of this article is currently not available via ORA.
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