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Fourier transformed large amplitude square−wave voltammetry as an alternative to impedance spectroscopy: Evaluation of resistance‚ capacitance and electrode kinetic effects via an heuristic approach

Abstract:: A detailed simulation of Fourier transformed large amplitude square-wave voltammetry is presented in the frequency domain for the process Red reversible arrow Ox+e(-). The simulation takes into account the influence of the electrode kinetics (Butler - Volmer model), uncompensated resistance (R-u) and double layer capacitance (C-dl). Of particular significance is the prediction that the even harmonic responses are only detected in the presence of quasi-reversibility or uncompensated resistance...
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APA Style

Sher, A., Bond, A., Gavaghan, D., Gillow, K., Duffy, N., Guo, S., & Zhang, J. (2005). Fourier transformed large amplitude square−wave voltammetry as an alternative to impedance spectroscopy: Evaluation of resistance‚ capacitance and electrode kinetic effects via an heuristic approach. Electroanalysis, 17(15), 1450–1462.

MLA Style

Sher, A., et al. “Fourier Transformed Large Amplitude Square−Wave Voltammetry as an Alternative to Impedance Spectroscopy: Evaluation of Resistance‚ Capacitance and Electrode Kinetic Effects via an Heuristic Approach.” Electroanalysis, vol. 17, no. 15, 2005, pp. 1450–62.

Chicago Style

Sher, A, A Bond, D Gavaghan, K Gillow, N Duffy, S Guo, and J Zhang. 2005. “Fourier Transformed Large Amplitude Square−Wave Voltammetry as an Alternative to Impedance Spectroscopy: Evaluation of Resistance‚ Capacitance and Electrode Kinetic Effects via an Heuristic Approach.” Electroanalysis 17 (15): 1450–62.
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+ Bond, A More by this author

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+ Gavaghan, D More by this author

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+ Gillow, K More by this author

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+ Duffy, N More by this author

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Bibliographic Details

Journal:: Electroanalysis
Volume:: 17
Issue:: 15
Pages:: 1450-1462
Publication date:: 2005-08-01

Item Description

UUID:: uuid:c98b055b-6563-4ae1-a90b-79b089754f02
Local pid:: cs:4262
Deposit date:: 2015-03-31

Terms of use

Copyright date:: 2005

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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