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A finite-element method for determining ohmic distortion of current-voltage curves at hydrodynamic electrodes

Abstract:

A finite-element method is described that predicts the effects of ohmic distortion of current-voltage curves for arbitrary cell and hydrodynamic electrode geometries using the widely available circuit analysis program SPICE. Simulated and experimental data are presented for a channel electrode flow cell showing the displacement of the half-wave potential and the potential-dependent error in the Tafel slope for the case of an electrochemically reversible electrode reaction. Error curves are pr...

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Publication status:
Published

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Publisher copy:
10.1002/elan.1140050108

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Institution:
University of Oxford
Role:
Author
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Institution:
University of Oxford
Role:
Author
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Institution:
University of Oxford
Role:
Author
Journal:
Electroanalysis
Volume:
5
Issue:
1
Pages:
41-46
Publication date:
1993-01-01
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
Source identifiers:
44038
Keywords:
Pubs id:
pubs:44038
UUID:
uuid:c967b8ad-ea29-46aa-9b75-1f20e54be05b
Local pid:
pubs:44038
Deposit date:
2012-12-19

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