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A toolbox for parameter-free predictions of solid-state properties of monodisperse glassy polymers with frozen-in molecular orientation

Abstract:

This study presents a toolbox for the prediction of birefringence and craze initiation stress in oriented monodisperse linear amorphous polymers. The toolbox is assembled from a previously proposed melt-solid constitutive model that provides the necessary residual stress components required for predictions of birefringence and craze initiation stress. The Likhtman-McLeish theory for linear rheology of entangled polymers is used to generate the low reduced frequency part of the linear viscoela...

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Publication status:
Published

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Publisher copy:
10.1002/polb.23196

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Role:
Author
Journal:
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS More from this journal
Volume:
50
Issue:
24
Pages:
1748-1756
Publication date:
2012-12-01
DOI:
EISSN:
1099-0488
ISSN:
0887-6266
Language:
English
Keywords:
Pubs id:
pubs:367000
UUID:
uuid:c94221fa-afc5-40e1-97e9-75d44ce85e02
Local pid:
pubs:367000
Source identifiers:
367000
Deposit date:
2013-11-16

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