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Interstitial modification of palladium nanoparticles with boron atoms as a green catalyst for selective hydrogenation.

Abstract:

Lindlar catalysts comprising of palladium/calcium carbonate modified with lead acetate and quinoline are widely employed industrially for the partial hydrogenation of alkynes. However, their use is restricted, particularly for food, cosmetic and drug manufacture, due to the extremely toxic nature of lead, and the risk of its leaching from catalyst surface. In addition, the catalysts also exhibit poor selectivities in a number of cases. Here we report that a non-surface modification of palladi...

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Publisher copy:
10.1038/ncomms6787

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Journal:
Nat Commun More from this journal
Volume:
5
Pages:
5787
Publication date:
2014-01-01
DOI:
EISSN:
2041-1723
Language:
English
Pubs id:
pubs:500746
UUID:
uuid:c92d4501-0925-4c4a-aa54-b5f42d5f4fff
Local pid:
pubs:500746
Source identifiers:
500746
Deposit date:
2014-12-27

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