Interstitial modification of palladium nanoparticles with boron atoms as a green catalyst for selective hydrogenation.

Journal article

Lindlar catalysts comprising of palladium/calcium carbonate modified with lead acetate and quinoline are widely employed industrially for the partial hydrogenation of alkynes. However, their use is restricted, particularly for food, cosmetic and drug manufacture, due to the extremely toxic nature of lead, and the risk of its leaching from catalyst surface. In addition, the catalysts also exhibit poor selectivities in a number of cases. Here we report that a non-surface modification of palladi...

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Authors: Chan, C; Mahadi, A; Li, M; Corbos, E; Tang, C

• Journal: Nat Commun
• Volume: 5
• Pages: 5787
• Publication date: 2014-01-01
• DOI: 10.1038/ncomms6787
• EISSN: 2041-1723
• Language: English