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Structure and bonding in the isoelectronic series CnHnP5-n+: is phosphorus a carbon copy?

Abstract:: The relative stabilities of different isomers of the isoelectronic series C(n)H(n)P(5-n)(+) have been investigated using G3X theory. The results indicate that all species containing one or more phosphorus atom adopt a three-dimensional nido geometry, in marked contrast to the planar structure favoured by the all-carbon analogue. Within isomeric nido clusters, a strong correlation between total energy and the nucleus-independent chemical shift (NICS) indicates that three-dimensional aromaticit...
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Publication status:: Published

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APA Style

Pantazis, D., McGrady, J., Lynam, J., Russell, C., & Green, M. (2004). Structure and bonding in the isoelectronic series CnHnP5-n+: is phosphorus a carbon copy? Dalton Transactions (Cambridge, England : 2003), 14, 2080–2086.

MLA Style

Pantazis, D., et al. “Structure and Bonding in the Isoelectronic Series CnHnP5-n+: Is Phosphorus a Carbon Copy?” Dalton Transactions (Cambridge, England : 2003), no. 14, 2004, pp. 2080–86.

Chicago Style

Pantazis, D, J McGrady, J Lynam, C Russell, and M Green. 2004. “Structure and Bonding in the Isoelectronic Series CnHnP5-n+: Is Phosphorus a Carbon Copy?” Dalton Transactions (Cambridge, England : 2003), no. 14: 2080–86.
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Publisher copy:: 10.1039/b405609d

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+ Pantazis, D More by this author

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+ McGrady, J More by this author

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+ Lynam, J More by this author

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+ Russell, C More by this author

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+ Green, M More by this author

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Bibliographic Details

Journal:: Dalton transactions (Cambridge, England : 2003)
Issue:: 14
Pages:: 2080-2086
Publication date:: 2004-07-01
DOI:: 10.1039/b405609d
EISSN:: 1477-9234
ISSN:: 1477-9226

Item Description

Language:: English
Pubs id:: pubs:50397
UUID:: uuid:c92cae16-96ae-4832-b115-c359fc81c3f8
Local pid:: pubs:50397
Source identifiers:: 50397
Deposit date:: 2012-12-19

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Copyright date:: 2004

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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