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CHRONOAMPEROMETRY AT CHANNEL ELECTRODES - EXPERIMENTAL APPLICATIONS OF DOUBLE ELECTRODES

Abstract:

Applications of transient experiments using double-channel electrodes are reported. The current response of a downstream detector electrode to a potential step at an upstream generator electrode is found to be in good agreement with theory. Such experiments are used to (i) demonstrate that the diffusion coefficient of the electrogenerated radical anion of p-chloranil in acetonitrile solution is 0.94 × 10-5 cm2 s-1, which contrasts markedly with that of the parent material (1.75 × 10-5 cm2 S-1...

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Publication status:
Published

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Publisher copy:
10.1021/j100060a036

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY More from this journal
Volume:
98
Issue:
9
Pages:
2446-2451
Publication date:
1994-03-03
DOI:
EISSN:
1541-5740
ISSN:
0022-3654
Pubs id:
pubs:44443
UUID:
uuid:c9053a1c-fe61-4753-a206-0936824b2064
Local pid:
pubs:44443
Source identifiers:
44443
Deposit date:
2012-12-19

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