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Catalytic enantioselective total synthesis of hodgkinsine B.

Abstract:
The power of palladium: The total synthesis of the alkaloid hodgkinsine B has been achieved with just six isolated intermediates and only four chromatographic operations. The route involves a palladium-catalyzed enantioselective desymmetrizing N-allylation of meso- chimonanthine to establish the absolute configuration and elaboration of the desymmetrized core by a diastereoselective palladium-catalyzed α-oxindole arylation. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/anie.201103864
Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
50
Issue:
39
Pages:
9116-9119
Publication date:
2011-09-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Language:
English
Keywords:
Pubs id:
pubs:175236
UUID:
uuid:c8ff5898-3c96-4318-afc5-3b5ca78e3b19
Local pid:
pubs:175236
Source identifiers:
175236
Deposit date:
2012-12-19

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