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Time-resolved CIDNP study of non-native states of bovine and human alpha-lactalbumins.

Abstract:

The reaction mechanism and details of the formation of CIDNP (chemically induced dynamic nuclear polarization) in the photoreactions of the aromatic dye 2,2'-dipyridyl with non-native states of bovine and human alpha-lactalbumins (BLA and HLA) in aqueous solution have been studied using the time-resolved CIDNP technique. Non-native states have been obtained at pH 2 in the presence of 0, 8, and 10 M urea-d(4) and at pH 6.7 in the presence of 10 M urea-d(4). The dependence of the geminate CIDNP...

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Publication status:
Published

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Publisher copy:
10.1021/jp045367v

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
The journal of physical chemistry. B
Volume:
109
Issue:
12
Pages:
5912-5918
Publication date:
2005-03-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:c8fb6315-09a4-47c5-8897-c1dc79c1faf1
Source identifiers:
33550
Local pid:
pubs:33550

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