An unprecedented regiospecific attack of phosphorus nucleophiles at Cα of the allenyl ligand in [Fe2(CO)6(μ-PPh2){μ-η 1:η2 α,β-(H)C α=Cβ=CγH2}] - ORA - Oxford University Research Archive

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An unprecedented regiospecific attack of phosphorus nucleophiles at Cα of the allenyl ligand in [Fe2(CO)6(μ-PPh2){μ-η 1:η2 α,β-(H)C α=Cβ=CγH2}]

Abstract:: The binuclear allenyl complex [Fe2(CO)6(μ-PPh2)-{μ-η1 : η2-(H)Cα=Cβ=C γH2}] 1 reacts with PPh2H and PPhH2 to afford [Fe2(CO)6(μ-PPh2){μ-η1 : η2-(Me)C=CH(PPh2)}] 2 and [{Fe2(CO)6(μ-PPh2)-(μ-η1 : η2-(Me)C=CH)}2PPh] 3 respectively both of which contain μ-η1 : η2-coordinated phosphino-substituted alkenyl ligands formed via an unprecedented regiospecific attack of phosphorus nucleophiles at Caα of the μ-η1 : η2-coordinated allenyl followed by a facile 1,4-hydrogen migration.

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APA Style

Doherty, S., Elsegood, M., Clegg, W., Scanlan, T., & Rees, N. (2016). An unprecedented regiospecific attack of phosphorus nucleophiles at Cα of the allenyl ligand in [Fe2(CO)6(μ-PPh2){μ-η 1:η2 α,β-(H)C α=Cβ=CγH2}]. Chemical Communications, 13, 1545–1546.

MLA Style

Doherty, S., et al. “An Unprecedented Regiospecific Attack of Phosphorus Nucleophiles at Cα of the Allenyl Ligand in [Fe2(CO)6(μ-PPh2){μ-η 1:η2 α,β-(H)C α=Cβ=CγH2}].” Chemical Communications, no. 13, 2016, pp. 1545–46.

Chicago Style

Doherty, S, M Elsegood, W Clegg, T Scanlan, and N Rees. 2016. “An Unprecedented Regiospecific Attack of Phosphorus Nucleophiles at Cα of the Allenyl Ligand in [Fe2(CO)6(μ-PPh2){μ-η 1:η2 α,β-(H)C α=Cβ=CγH2}].” Chemical Communications, no. 13: 1545–46.
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+ Doherty, S More by this author

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+ Elsegood, M More by this author

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+ Clegg, W More by this author

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+ Scanlan, T More by this author

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+ Rees, N More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Inorganic Chemistry

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Author

Bibliographic Details

Journal:: Chemical Communications
Issue:: 13
Pages:: 1545-1546
Publication date:: 1996-01-01
ISSN:: 1359-7345
Source identifiers:: 118884

Item Description

Language:: English
Pubs id:: pubs:118884
UUID:: uuid:c8db88aa-5d14-4a29-8a22-c80ad587ff9f
Local pid:: pubs:118884
Deposit date:: 2013-02-20

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Copyright date:: 1996

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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