Journal article
An unprecedented regiospecific attack of phosphorus nucleophiles at Cα of the allenyl ligand in [Fe2(CO)6(μ-PPh2){μ-η 1:η2 α,β-(H)C α=Cβ=CγH2}]
- Abstract:
- The binuclear allenyl complex [Fe2(CO)6(μ-PPh2)-{μ-η1 : η2-(H)Cα=Cβ=C γH2}] 1 reacts with PPh2H and PPhH2 to afford [Fe2(CO)6(μ-PPh2){μ-η1 : η2-(Me)C=CH(PPh2)}] 2 and [{Fe2(CO)6(μ-PPh2)-(μ-η1 : η2-(Me)C=CH)}2PPh] 3 respectively both of which contain μ-η1 : η2-coordinated phosphino-substituted alkenyl ligands formed via an unprecedented regiospecific attack of phosphorus nucleophiles at Caα of the μ-η1 : η2-coordinated allenyl followed by a facile 1,4-hydrogen migration.
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Bibliographic Details
- Journal:
- Chemical Communications
- Issue:
- 13
- Pages:
- 1545-1546
- Publication date:
- 1996-01-01
- ISSN:
-
1359-7345
- Source identifiers:
-
118884
Item Description
- Language:
- English
- Pubs id:
-
pubs:118884
- UUID:
-
uuid:c8db88aa-5d14-4a29-8a22-c80ad587ff9f
- Local pid:
- pubs:118884
- Deposit date:
- 2013-02-20
Terms of use
- Copyright date:
- 1996
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