Journal article
Variable coordination modes and catalytic dehydrogenation of B-phenyl amine-boranes.
- Abstract:
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The chemistry ofN-substituted amine–boranes and their reactivity towards transition metal centres is well established but the chemistry ofB-substituted amine–boranes is not. Here we present the coordination chemistry of H2PhB·NMe3towards a range of Rh(I) fragments with different P–Rh–P ligand bite angles, {Rh(PiPr3)2}+, {Rh(PiBu3)2}+, {Rh(iPr2P(CH2)3PiPr2)}+, {Rh(Ph2P(CH2)nPPh2)}+(n= 3, 5), as characterised by NMR spectroscopy and single-crystal X-ray diffraction. This reveals a difference in...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Version of record, pdf, 1.8MB)
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- Publisher copy:
- 10.1039/c6dt00197a
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Authors
Funding
Rhodes Trust
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Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Dalton transactions (Cambridge, England : 2003) Journal website
- Volume:
- 45
- Pages:
- 6183-6195
- Publication date:
- 2016-02-01
- Acceptance date:
- 2016-02-23
- DOI:
- EISSN:
-
1477-9234
- ISSN:
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1477-9226
- Source identifiers:
-
609315
Item Description
- Language:
- English
- Pubs id:
-
pubs:609315
- UUID:
-
uuid:c8710eea-3274-4b8a-9a4a-39012d2b09cc
- Local pid:
- pubs:609315
- Deposit date:
- 2016-03-22
Terms of use
- Copyright holder:
- The Royal Society of Chemistry
- Copyright date:
- 2016
- Notes:
- © The Royal Society of Chemistry 2016 This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
- Licence:
- CC Attribution (CC BY)
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