Journal article
Variable coordination modes and catalytic dehydrogenation of B-phenyl amine-boranes.
- Abstract:
-
The chemistry ofN-substituted amine–boranes and their reactivity towards transition metal centres is well established but the chemistry ofB-substituted amine–boranes is not. Here we present the coordination chemistry of H2PhB·NMe3towards a range of Rh(I) fragments with different P–Rh–P ligand bite angles, {Rh(PiPr3)2}+, {Rh(PiBu3)2}+, {Rh(iPr2P(CH2)3PiPr2)}+, {Rh(Ph2P(CH2)nPPh2)}+(n= 3, 5), as characterised by NMR spectroscopy and single-crystal X-ray diffraction. This reveals a difference in...
Expand abstract
- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's version
Actions
Access Document
- Files:
-
-
(pdf, 1.8MB)
-
- Publisher copy:
- 10.1039/c6dt00197a
Why is the content I wish to access not available via ORA?
Bibliographic data (the information relating to research outputs) and full-text items (e.g. articles, theses, reports, etc.) arrive in ORA from several different sources. Unfortunately we are not able to make available the full-text for every research output.
Please contact the ORA team (
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
Content may be unavailable for the following four reasons
-
Version unsuitable
-
We have not obtained a suitable full-text for a given research output. See this page for more information.
-
Recently completed
-
Sometimes content is held in ORA but is unavailable for a fixed period of time to comply with the policies and wishes of rights holders.
-
Permissions
-
All content made available in ORA should comply with relevant rights, such as copyright. See this page for more information.
-
Clearance
-
Some thesis volumes scanned as part of the digitisation scheme funded by Dr Leonard Polonsky are currently unavailable due to sensitive material or uncleared third-party copyright content. We are attempting to contact authors whose theses are affected.
Alternative access to the full-text
You may be able to access the full-text directly from the publisher's website using the 'Publisher Copy' link in the 'Links & Downloads' box from a research output's ORA record page. This method may require an institutional or individual subscription to the journal/resource.
Authors
Funding
Rhodes Trust
More from this funder
Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Dalton transactions (Cambridge, England : 2003) Journal website
- Volume:
- 45
- Pages:
- 6183-6195
- Publication date:
- 2016-02-05
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- URN:
-
uuid:c8710eea-3274-4b8a-9a4a-39012d2b09cc
- Source identifiers:
-
609315
- Local pid:
- pubs:609315
Item Description
- Language:
- English
Terms of use
- Copyright holder:
- The Royal Society of Chemistry
- Copyright date:
- 2016
- Notes:
- © The Royal Society of Chemistry 2016 This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
If you are the owner of this record, you can report an update to it here: Report update to this record