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Variable coordination modes and catalytic dehydrogenation of B-phenyl amine-boranes.

Abstract:

The chemistry ofN-substituted amine–boranes and their reactivity towards transition metal centres is well established but the chemistry ofB-substituted amine–boranes is not. Here we present the coordination chemistry of H2PhB·NMe3towards a range of Rh(I) fragments with different P–Rh–P ligand bite angles, {Rh(PiPr3)2}+, {Rh(PiBu3)2}+, {Rh(iPr2P(CH2)3PiPr2)}+, {Rh(Ph2P(CH2)nPPh2)}+(n= 3, 5), as characterised by NMR spectroscopy and single-crystal X-ray diffraction. This reveals a difference in...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1039/c6dt00197a

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Priest, IK More by this author
Hooper, TN More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Rhodes Trust More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Dalton transactions (Cambridge, England : 2003) Journal website
Volume:
45
Pages:
6183-6195
Publication date:
2016-02-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:c8710eea-3274-4b8a-9a4a-39012d2b09cc
Source identifiers:
609315
Local pid:
pubs:609315
Language:
English

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