Journal article icon

Journal article

Kinetics and Thermodynamics of Redox Processes in Room Temperature Ionic Liquids: The Use of Voltammetry and the Disproportionation of Radical Cations of N,N-Dimethyl-p-phenylenediamine in 1-Butyl-3-methylimidazolium Tetrafluoroborate

Abstract:

The voltammetry of N,N-dimethyl-p-phenylenediamine, DMPD, in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tetrafluoroborate, [C4mim][BF4] is studied by means of microdisc voltammetry over a wide range of voltage scan rates incorporating the transition from linear to convergent diffusion. Two voltammetric waves were recorded corresponding to the formation of the radical cation DMPD+ and dication DMPD 2+; both are stable on the voltammetric time scale. Double potential s...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/je900770b

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF CHEMICAL AND ENGINEERING DATA More from this journal
Volume:
55
Issue:
6
Pages:
2219-2224
Publication date:
2010-06-01
DOI:
EISSN:
1520-5134
ISSN:
0021-9568
Language:
English
Pubs id:
pubs:60694
UUID:
uuid:c8437026-d37e-428f-b44d-091a5f50ecd3
Local pid:
pubs:60694
Source identifiers:
60694
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP