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Ferrocenylmethylphosphonate formation. Synthesis, spectroscopy and molecular structure

Abstract:
Reaction of ferrocenylmethanol, FcCH2OH, with β-cyano-N,N-diisopropyl chlorophosphoramidite in dichloromethane yields the ferrocenylmethylphosphonate derivative, FcCH2P(O)(N(iPr)2)(OCH2CH2CN), 2a. The crystal and molecular structure of 2a is presented. 31P NMR data suggest that this is formed from FcCH2OP(N(iPr)2)(OCH2CH2CN) via a Michaelis-Arbusov-type rearrangement. Similar behaviour was also observed for 1,2-phenylene chlorophosphite and diethyl chlorophosphite.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
POLYHEDRON More from this journal
Volume:
17
Issue:
22
Pages:
3817-3823
Publication date:
1998-01-01
DOI:
ISSN:
0277-5387
Language:
English
Keywords:
Pubs id:
pubs:115939
UUID:
uuid:c82ac853-4931-40d3-b2d9-f923f8f64caa
Local pid:
pubs:115939
Source identifiers:
115939
Deposit date:
2012-12-19

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