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Supported permethylindenyl titanium catalysts for the synthesis of disentangled ultra-high molecular weight polyethylene (disUHMWPE)

Abstract:

Novel permethylindenyl-phenoxide (PHENI*) ansa-metallocene titanium complexes have been synthesised and immobilised on inorganic solid supports to afford highly effective catalysts for slurry-phase ethylene polymerisation. When supported on solid polymethylaluminoxane these complexes were both extremely active (up to 3.7 × 106 gPE molTi−1 h...

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Publication status:
Published
Peer review status:
Peer reviewed

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0003-2062-9546
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0003-2044-9203
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Balliol College
Role:
Author
ORCID:
0000-0001-8054-8751
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications More from this journal
Volume:
57
Issue:
69
Pages:
8600-8603
Place of publication:
England
Publication date:
2021-08-09
Acceptance date:
2021-07-31
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pmid:
34365496
Language:
English
Keywords:
Pubs id:
1190296
Local pid:
pubs:1190296
Deposit date:
2021-10-14

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