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Journal article

Influence of ligand backbone flexibility in group 4 metal complexes of tetradentate mixed tertiary amine/alkoxide ligands

Abstract:

Simple epoxide ring opening chemistry using the cyclic secondary amine 1,4-diazacycloheptane or the related linear species N,N′- dimethylethylenediamine, and racemic (±)-3,3-dimethyl-1,2-epoxybutane gives access to the pendant alcohol functionalised ditertiary amine pro-ligands [HOCH(tBu)CH2N(R)CH2]2 (H 2L1: R2 = CH2CH2CH 2; H2L2: R2 = Me2). The contrasting reactions of H2L1 and H2L 2 towards homoleptic group 4 alkoxides highlight the crucial role of ligand backbone flexibility in complex for...

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Publication status:
Published

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Publisher copy:
10.1039/b608680b

Authors


Journal:
NEW JOURNAL OF CHEMISTRY
Volume:
31
Issue:
1
Pages:
135-142
Publication date:
2007-01-01
DOI:
EISSN:
1369-9261
ISSN:
1144-0546
Language:
English
Pubs id:
pubs:40173
UUID:
uuid:c77087cc-cd62-4804-8a05-486e0aa37ba1
Local pid:
pubs:40173
Source identifiers:
40173
Deposit date:
2012-12-19

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