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A PLATINUM-LINKED PORPHYRIN TRIMER AND A COMPLEMENTARY ALUMINUM TRIS[3-(4-PYRIDYL)ACETYLACETONATE] GUEST

Abstract:

A cyclic trimeric porphyrin host has been synthesised with alkyne-platinum-alkyne linkages; binding of the octahedral aluminium tris[3-(4-pyridyl)acetylacetonate] guest ligand into the complementary cavity of the host induces an asymmetry which is readily detected by NMR spectroscopy. The ligand complementarity unambiguously establishes the structure of this complex artificial receptor, but did not lead to an effective templated synthesis. A platinum-linked tetramer was also tentatively ident...

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Publication status:
Published

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Publisher copy:
10.1039/p19950002269

Authors


Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Issue:
18
Pages:
2269-2273
Publication date:
1995-09-21
DOI:
EISSN:
1364-5463
ISSN:
0300-922X
URN:
uuid:c759d09b-2edd-4e24-b636-ccb77f8c9639
Source identifiers:
51879
Local pid:
pubs:51879
Language:
English

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