- Abstract:
-
A cyclic trimeric porphyrin host has been synthesised with alkyne-platinum-alkyne linkages; binding of the octahedral aluminium tris[3-(4-pyridyl)acetylacetonate] guest ligand into the complementary cavity of the host induces an asymmetry which is readily detected by NMR spectroscopy. The ligand complementarity unambiguously establishes the structure of this complex artificial receptor, but did not lead to an effective templated synthesis. A platinum-linked tetramer was also tentatively ident...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/p19950002269
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
- Issue:
- 18
- Pages:
- 2269-2273
- Publication date:
- 1995-09-21
- DOI:
- EISSN:
-
1364-5463
- ISSN:
-
0300-922X
- URN:
-
uuid:c759d09b-2edd-4e24-b636-ccb77f8c9639
- Source identifiers:
-
51879
- Local pid:
- pubs:51879
- Language:
- English
- Copyright date:
- 1995
Journal article
A PLATINUM-LINKED PORPHYRIN TRIMER AND A COMPLEMENTARY ALUMINUM TRIS[3-(4-PYRIDYL)ACETYLACETONATE] GUEST
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