Journal article

Ene cyclisations of alpha-(prenyl)dialkylsilyloxy aldehydes: formation and oxidative cleavage of oxasilacyclohexanols.

Abstract:: A variety of routes are described for the synthesis of a-silyloxy aldehydes in which the silicon atom bears a prenyl side chain. These compounds are shown to undergo stereoselective carbonyl ene cyclisation under mildly Lewis acidic conditions and the derived silacycles are cleaved to afford single diastereomers of functionalised triols.

Publication status:: Published

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APA Style

Robertson, J., Hall, M., Stafford, P., & Green, S. (2003). Ene cyclisations of alpha-(prenyl)dialkylsilyloxy aldehydes: formation and oxidative cleavage of oxasilacyclohexanols. Organic and Biomolecular Chemistry, 1(21), 3758–3767.

MLA Style

Robertson, J., et al. “Ene Cyclisations of Alpha-(Prenyl)Dialkylsilyloxy Aldehydes: Formation and Oxidative Cleavage of Oxasilacyclohexanols.” Organic and Biomolecular Chemistry, vol. 1, no. 21, 2003, pp. 3758–67.

Chicago Style

Robertson, J, M Hall, P Stafford, and S Green. 2003. “Ene Cyclisations of Alpha-(Prenyl)Dialkylsilyloxy Aldehydes: Formation and Oxidative Cleavage of Oxasilacyclohexanols.” Organic and Biomolecular Chemistry 1 (21): 3758–67.
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Publisher copy:: 10.1039/b306922m

Authors

+ Robertson, J More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Hall, M More by this author

Role:: Author

+ Stafford, P More by this author

Role:: Author

+ Green, S More by this author

Role:: Author

Journal:: Organic and biomolecular chemistry More from this journal
Volume:: 1
Issue:: 21
Pages:: 3758-3767
Publication date:: 2003-11-01
DOI:: 10.1039/b306922m
EISSN:: 1477-0539
ISSN:: 1477-0520

Language:: English
Pubs id:: pubs:55234
UUID:: uuid:c718e6aa-56c0-47b3-9bbf-b23e8d71c6c0
Local pid:: pubs:55234
Source identifiers:: 55234
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2003

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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