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Journal article

Microwave activation in ionic liquids induces high temperature-high speed electrochemical processes.

Abstract:
Self-focusing of intense microwave radiation at the tip of a 25 microm diameter platinum disk microelectrode immersed into the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM(+)PF(6)(-)) containing 1 mM ferrocene causes dramatically (two orders of magnitude) enhanced voltammetric current signals and temperatures in excess of 600 K (at the electrode surface)--extreme conditions sufficient for condensed phase pyrolysis processes to occur.
Publication status:
Published

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Publisher copy:
10.1039/b410655e

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Chemical Communications
Issue:
24
Pages:
2816-2817
Publication date:
2004-12-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
39299
Language:
English
Pubs id:
pubs:39299
UUID:
uuid:c6f486da-0197-44f3-9704-126ef27d7323
Local pid:
pubs:39299
Deposit date:
2012-12-19

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