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Self-assembled xanthate-transition metal polyether macrocycles and cryptands

Abstract:

The synthesis of novel dinuclear nickel(II)-xanthate polyether macrocycles and dinuclear cobalt(III)-xanthate polyether cryptands is reported. The assemblies have been characterised by a range of spectroscopic techniques and in one case by X-ray crystal structure determination. Electrospray mass spectrometry provided evidence that the dinuclear nickel(II)-xanthate macrocycles form adducts with Group I metal cations and methyl viologen (MV2+). The dinuclear cobalt(III)-xanthate cryptands also ...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
POLYHEDRON
Volume:
22
Issue:
5
Pages:
795-801
Publication date:
2003-03-01
DOI:
ISSN:
0277-5387
Source identifiers:
38617
Language:
English
Keywords:
Pubs id:
pubs:38617
UUID:
uuid:c6e29592-32b9-43e4-b99b-a25130d82abd
Local pid:
pubs:38617
Deposit date:
2012-12-19

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