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PHYSICAL-PROPERTIES OF METAL CLUSTER COMPOUNDS .5. MAGNETIC MEASUREMENTS ON LOW-NUCLEARITY RUTHENIUM CARBONYL CLUSTERS

Abstract:
We present magnetic susceptibility and magnetization measurements on a series of low-nuclearity (n = 3 - 6) ruthenium carbonyl clusters. It is shown that even these very small metal cluster have a fraction of unpaired spin density leading to a low-temperature divergent susceptibility and a magnetization that is far from saturated in fields up to 5 tesla. The effect of CO adsorption on the magnetic properties of a bare cluster is discussed. © 1988.
Publication status:
Published

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Journal:
SOLID STATE COMMUNICATIONS
Volume:
66
Issue:
9
Pages:
913-916
Publication date:
1988-06-01
DOI:
ISSN:
0038-1098
Source identifiers:
46486
Language:
English
Pubs id:
pubs:46486
UUID:
uuid:c6d07fe1-e8d4-4bb6-aac0-5f59f552ed20
Local pid:
pubs:46486
Deposit date:
2012-12-19

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