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Journal article

3-HYDROXYMUSCARINES FROM L-RHAMNOSE

Abstract:
No protection is necessary for the synthesis of the muscarine analogue 3R-3-hydroxymuscarine from L-rhamnose; a sole silyl ether protecting group is required for the synthesis of 3S-3-hydroxymuscarine. Efficient construction of the tetrahydrofuran ring can be achieved either by ring contraction of the α-triflate of δ-rhamnonolactone, or by ring opening and closing of the α-triflate of γ-rhamnonolactone. © 1993.
Publication status:
Published

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Journal:
TETRAHEDRON
Volume:
49
Issue:
16
Pages:
3343-3358
Publication date:
1993-04-16
DOI:
ISSN:
0040-4020
URN:
uuid:c66d0c74-f3ed-41ec-b119-b41455d086fd
Source identifiers:
44100
Local pid:
pubs:44100
Language:
English

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