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Journal article

Facile synthesis of interstitial metal nitrides with the filled beta-manganese structure

Abstract:

A new family of nitrides, Ni2-xM′xMo3N (M′=Co or Pd; 0≤x≤1.5), has been prepared pure by nitridation of commercially available crystalline metal oxides under reducing conditions (10% H2 in N2). The simple synthesis employs standard solid-state techniques and does not require the preparation of reactive precursors. Substitution of Ni by Co or Pd leads to a linear increase of the unit cell volume with composition. The temperature, composition, and magnetic-field dependence of the molar magnetis...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
172
Issue:
1
Pages:
138-147
Publication date:
2003-04-01
DOI:
ISSN:
0022-4596
Language:
English
Keywords:
Pubs id:
pubs:38648
UUID:
uuid:c63e6ad7-82cf-4cb9-bfb5-df43807163b3
Local pid:
pubs:38648
Source identifiers:
38648
Deposit date:
2012-12-19

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