Journal article
Facile synthesis of interstitial metal nitrides with the filled beta-manganese structure
- Abstract:
-
A new family of nitrides, Ni2-xM′xMo3N (M′=Co or Pd; 0≤x≤1.5), has been prepared pure by nitridation of commercially available crystalline metal oxides under reducing conditions (10% H2 in N2). The simple synthesis employs standard solid-state techniques and does not require the preparation of reactive precursors. Substitution of Ni by Co or Pd leads to a linear increase of the unit cell volume with composition. The temperature, composition, and magnetic-field dependence of the molar magnetis...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- JOURNAL OF SOLID STATE CHEMISTRY
- Volume:
- 172
- Issue:
- 1
- Pages:
- 138-147
- Publication date:
- 2003-04-01
- DOI:
- ISSN:
-
0022-4596
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:38648
- UUID:
-
uuid:c63e6ad7-82cf-4cb9-bfb5-df43807163b3
- Local pid:
- pubs:38648
- Source identifiers:
-
38648
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2003
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