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A complete numerical simulation of the techniques of alternating current linear sweep and cyclic voltammetry: analysis of a reversible process by conventional and fast Fourier transform methods

Abstract:

We describe the method of achieving the first completely general simulation of ac linear sweep and cyclic voltammetry making use of the fully implicit Richtmyer modification (FIRM) method. The simulation technique is applied to a reversible process under conditions where a sinusoidal waveform of any amplitude is superimposed onto the dc potential which is swept at a finite scan rate. Results, where possible, are compared with the existing theory derived at constant dc potential to confirm the...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Computer Science
Role:
Author
Publisher:
Elsevier
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
480
Issue:
1-2
Pages:
133-149
Publication date:
2000-01-25
DOI:
ISSN:
0022-0728
Language:
English
Keywords:
Pubs id:
pubs:274422
UUID:
uuid:c6102d59-1ecc-462c-b811-7a59ab86673c
Local pid:
pubs:274422
Source identifiers:
274422
Deposit date:
2012-12-19

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