- Abstract:
-
Diffusion problems encountered for the case of electrochemical conversion of microdroplets of an electroactive oil deposited on an electrode are studied by the dual reciprocity finite element simulation method (DRM). Three plausible mechanistic models are compared. For a microdroplet of electroactive material A) the electrochemical reaction commences from the oil-electrode surface interphase; B) there is rapid charge conduction over the droplet surface so that ion insertion occurs from the dr...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1002/1521-4109(200009)12:13<1012::AID-ELAN1012>3.0.CO;2-0
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- Journal:
- ELECTROANALYSIS
- Volume:
- 12
- Issue:
- 13
- Pages:
- 1012-1016
- Publication date:
- 2000-09-05
- DOI:
- EISSN:
-
1521-4109
- ISSN:
-
1040-0397
- URN:
-
uuid:c5dee266-abcc-49cf-9a67-0fe2cc793bc1
- Source identifiers:
-
37620
- Local pid:
- pubs:37620
- Copyright date:
- 2000
Journal article
Voltammetry of electroactive oil droplets. Part I: Numerical modelling for three mechanistic models using the dual reciprocity finite element method
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