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Voltammetry of electroactive oil droplets. Part I: Numerical modelling for three mechanistic models using the dual reciprocity finite element method

Abstract:

Diffusion problems encountered for the case of electrochemical conversion of microdroplets of an electroactive oil deposited on an electrode are studied by the dual reciprocity finite element simulation method (DRM). Three plausible mechanistic models are compared. For a microdroplet of electroactive material A) the electrochemical reaction commences from the oil-electrode surface interphase; B) there is rapid charge conduction over the droplet surface so that ion insertion occurs from the dr...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
ELECTROANALYSIS
Volume:
12
Issue:
13
Pages:
1012-1016
Publication date:
2000-09-05
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:c5dee266-abcc-49cf-9a67-0fe2cc793bc1
Source identifiers:
37620
Local pid:
pubs:37620

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