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Ferrimagnetism as a consequence of unusual cation ordering in the perovskite SrLa2FeCoSbO9

Abstract:

A polycrystalline sample of SrLa2FeCoSbO9 has been prepared in a solid-state reaction and studied by a combination of electron microscopy, magnetometry, Mössbauer spectroscopy, X-ray diffraction and neutron diffraction. The compound adopts a monoclinic (space group P21/n; a = 5.6218(6), b = 5.6221(6), c = 7.9440(8) Å, β = 90.050(7) ° at 300 K) perovskite-like crystal structure with two crystallographically distinct six-coordinate sites. One of these sites is occupied by ⅔ Co2+, ⅓ Fe3+ and the...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/acs.inorgchem.8b01012

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
St Catherines College
Hendrickx, M More by this author
Hadermann, J More by this author
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Publisher:
American Chemical Society Publisher's website
Journal:
Inorganic Chemistry Journal website
Volume:
57
Issue:
12
Pages:
7438–7445
Publication date:
2018-05-29
Acceptance date:
2018-05-15
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Pubs id:
pubs:847806
URN:
uri:c5bfed97-3d58-4798-ac94-49e035357efa
UUID:
uuid:c5bfed97-3d58-4798-ac94-49e035357efa
Local pid:
pubs:847806

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